This report shows the 2014 top student in each HSC subject as awarded by the NSW Education Standards Authority. Students must achieve a band 6 or band E4 result in the relevant subject to appear in this list. Rankings are calculated from student HSC marks in the subject, or, where this results in a tie, from the average of the students' examination and assessment marks.
This report is equivalent to the Subject Top Achievers report after applying the filter "Rank equals 1".
| 1 | Aboriginal Studies | Pulver, Luke | Hunter School of the Performing Arts | Broadmeadow |
| 2 | Agriculture | Tan, Reynard Ezekiel | Hurlstone Agricultural High School | Glenfield |
| 3 | Ancient History | Penales, Stephanie | Mt Carmel Catholic High School | Varroville |
| 4 | Arabic Continuers | Ibrahim, Shumokh | Saturday School of Comm. Lang. Birrong Girls High School | Birrong |
| 5 | Arabic Extension | Benhaddou, Mouemina | Saturday School of Comm. Lang. Birrong Girls High School | Birrong |
| 6 | Armenian Continuers | Darbinian, Michelle | Saturday School of Comm. Lang. Chatswood High School | Chatswood |
| 7 | Automotive Examination | Deall, Tristan Scott | Northern Sydney Institute Hornsby College | Hornsby |
| 8 | Biology | Goyal, Abhishek | James Ruse Agricultural High School | Carlingford |
| 9 | Business Services Examination | Hasbany, Jessica | Cerdon College | Merrylands |
| 10 | Business Studies | Reidy, Nathan John | St Pius X College | Chatswood |
| 11 | Chemistry | Fridgant, Joshua Adam | Canberra Grammar School | Red Hill |
| 12 | Chinese Background Speakers | Si, Rufei S Sophie | St Ives High School | St Ives |
| 13 | Chinese Beginners | Warren, Leon Karbic | St Pius X College | Chatswood |
| 14 | Chinese Continuers | Pannach, Sian | Australian International School Hong Kong | Hong Kong |
| 15 | Chinese Extension | Taranto, Gianluca Michael | St Ignatius College | Lane Cove |
| 16 | Classical Greek Continuers | Kynaston, Grant | Sydney Grammar School | Darlinghurst |
| 17 | Classical Greek Extension | Kynaston, Grant | Sydney Grammar School | Darlinghurst |
| 18 | Classical Hebrew Continuers | Schapiro, Raizel | Kesser Torah College | Dover Heights |
| 19 | Classical Hebrew Extension | Schapiro, Raizel | Kesser Torah College | Dover Heights |
| 20 | Community and Family Studies | Tyler, Rebecca Louise | Merewether High School | Broadmeadow |
| 21 | Construction Examination | McMullen, Riley Lawrence | The Riverina Anglican College | Wagga Wagga |
| 22 | Croatian Continuers | Mihaljevic, Mia | Saturday School of Comm. Lang. Kogarah High School | Kogarah |
| 23 | Dance | Goodfellow, Jessica Elizabeth | Newtown High School of Performing Arts | Newtown |
| 24 | Dance | Holloway, Mikala Dane | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale |
| 25 | Dance | Mulholland, Bridget | Trinity Catholic College Lismore | Lismore |