This is the NSW HSC honour Roll, listing every award or prize won by New South Wales HSC students in 2014, along with their school and subject details.
The report includes all Distinguished Achiever awards, All Rounder awards, and Subject Top Achiever awards (including rankings). First in Course awards are shown as Subject Top Achiever awards with a ranking of '1' i.e. first place.
| 1 | Aafjes, Mitchell Blake | Hastings Secondary College Westport Campus | Port Macquarie | Industrial Technology | DA | |
| 2 | Aaron, Alexis | Moriah College | Queens Park | All-rounder | ||
| 3 | Aaron, Alexis | Moriah College | Queens Park | Drama | DA | |
| 4 | Aaron, Alexis | Moriah College | Queens Park | English (Advanced) | DA | |
| 5 | Aaron, Alexis | Moriah College | Queens Park | Legal Studies | DA | |
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| 6 | Aaron, Alexis | Moriah College | Queens Park | Mathematics General 2 | DA | |
| 7 | Aaron, Alexis | Moriah College | Queens Park | Studies of Religion II | DA | |
| 8 | Aarons, Ilan | Killara High School | Killara | Mathematics General 2 | DA | |
| 9 | Abagi, Mitchell Sam | Barker College | Hornsby | Mathematics | DA | |
| 10 | Abagi, Mitchell Sam | Barker College | Hornsby | Music 2 | DA | |
| 11 | Abagi, Mitchell Sam | Barker College | Hornsby | Music Extension | DA | |
| 12 | Abagi, Mitchell Sam | Barker College | Hornsby | Personal Development, Health and Physical Education | DA | |
| 13 | Abasseri, Tarek | Malek Fahd Islamic School | Greenacre | English (Advanced) | DA | |
| 14 | Abasseri, Tarek | Malek Fahd Islamic School | Greenacre | English Extension 1 | DA | |
| 15 | Abba, Imogen May | Newtown High School of Performing Arts | Newtown | English (Advanced) | DA | |
| 16 | Abba, Imogen May | Newtown High School of Performing Arts | Newtown | English Extension 1 | DA | |
| 17 | Abbas, Sara | Macarthur Girls High School | Parramatta | Arabic Continuers | DA | |
| 18 | Abbas, Sara | Macarthur Girls High School | Parramatta | Community and Family Studies | DA | |
| 19 | Abbey, Isabel | Stella Maris College | Manly | Design and Technology | DA | |
| 20 | Abbey, Isabel | Stella Maris College | Manly | Mathematics General 2 | DA | |
| 21 | Abbey, Isabel | Stella Maris College | Manly | Textiles and Design | DA | |
| 22 | Abbey, Isabel | Stella Maris College | Manly | Visual Arts | DA | |
| 23 | Abbott, Gabrielle | Oxley College | Burradoo | Biology | DA | |
| 24 | Abbott, Savannah | St John Paul II Catholic College Nirimba | Quakers Hill | Personal Development, Health and Physical Education | DA | |
| 25 | Abbott-Monnox, Ruby | Newcastle Grammar School | Newcastle | Mathematics General 2 | DA | |