This report lists the winners of Certificates of Distinction and Certificates of Merit for 2010, along with the school that they attended.
These certificates are awarded to students who achieve at least 150 points (Certificate of Merit) or 190 points (Certificate of Distinction) across 20 year 11 and year 12 course units or equivalents, of which 10 are at year 12 level.
Formerly these awards were named Certificates of Commendation (2012-2015) or Certificates of Excellence (prior to 2012), and were based on achievements of at least 20 'A' grades in course units or equivalents.
| 1 | Cert of Excellence | ABBOTT, JAMES SAMUEL | Hale School | Wembley Downs |
| 2 | Cert of Excellence | ABWEH, MAHA | Lake Joondalup Baptist College | Joondalup |
| 3 | Cert of Excellence | ADAM, RYAN JAMES | Mandurah Catholic College | Mandurah |
| 4 | Cert of Excellence | ADAMS, SAMANTHA KATE | Living Waters Lutheran College | Rockingham |
| 5 | Cert of Excellence | ADLER, CALLAN BENJAMIN | Hale School | Wembley Downs |
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| 6 | Cert of Excellence | ADSHEAD, MORGAN ELIZABETH | Lynwood Senior High School | Parkwood |
| 7 | Cert of Excellence | AH TECK, JASON | Christ Church Grammar School | Claremont |
| 8 | Cert of Excellence | AITKEN, ELIZABETH CATHERINE | Perth Modern School | Subiaco |
| 9 | Cert of Excellence | AITKEN, EMILY KATE | Methodist Ladies College | Claremont |
| 10 | Cert of Excellence | AKL, JESSICA | Bunbury Catholic College | Bunbury |
| 11 | Cert of Excellence | ALBERGHINI, JULIA MIKAELA | Methodist Ladies College | Claremont |
| 12 | Cert of Excellence | ALBERS, RACHAEL JANE | Ursula Frayne Catholic College | Victoria Park |
| 13 | Cert of Excellence | ALDERDICE, COURTNEY LEE | Lumen Christi College | Gosnells |
| 14 | Cert of Excellence | ALESSANDRINO, EMILY MARIA | Woodvale Secondary College | Woodvale |
| 15 | Cert of Excellence | ALEXANDER, ANEEKA | St Marys Anglican Girls School | Karrinyup |
| 16 | Cert of Excellence | ALEXI, JOANNA | Padbury Senior High School | Padbury |
| 17 | Cert of Excellence | ALFONSI, EMILY KATHRINE | Seton Catholic College | Hamilton Hill |
| 18 | Cert of Excellence | ALI, MARLEY SHARAZ | Emmanuel Catholic College | Success |
| 19 | Cert of Excellence | ALLAN, BRETT CAMERON | Sacred Heart College | Wangara |
| 20 | Cert of Excellence | ALLEN, EMILY FRANCES | Carine Senior High School | Carine |
| 21 | Cert of Excellence | AMARAL, NATHAN ROSS | Wesley College | South Perth |
| 22 | Cert of Excellence | ANDINATA, YONGKY | Applecross Senior High School | Ardross |
| 23 | Cert of Excellence | ANGKOLA, ELIZABETH | Sevenoaks Senior College | Cannington |
| 24 | Cert of Excellence | ANSELL, MEGAN ELISE | St Brigids College | Lesmurdie |
| 25 | Cert of Excellence | ARANCINI, NATASHA MARIE | Penrhos College | Como |