This report lists the winners of Certificates of Distinction and Certificates of Merit for 2010, along with the school that they attended.
These certificates are awarded to students who achieve at least 150 points (Certificate of Merit) or 190 points (Certificate of Distinction) across 20 year 11 and year 12 course units or equivalents, of which 10 are at year 12 level.
Formerly these awards were named Certificates of Commendation (2012-2015) or Certificates of Excellence (prior to 2012), and were based on achievements of at least 20 'A' grades in course units or equivalents.
| 1 | Cert of Excellence | ABBOTT, JAMES SAMUEL | Hale School | Wembley Downs |
| 2 | Cert of Excellence | ABWEH, MAHA | Lake Joondalup Baptist College | Joondalup |
| 3 | Cert of Excellence | ADAM, RYAN JAMES | Mandurah Catholic College | Mandurah |
| 4 | Cert of Excellence | ADAMS, SAMANTHA KATE | Living Waters Lutheran College | Warnbro |
| 5 | Cert of Excellence | ADLER, CALLAN BENJAMIN | Hale School | Wembley Downs |
| 6 | Cert of Excellence | ADSHEAD, MORGAN ELIZABETH | Lynwood Senior High School | Parkwood |
| 7 | Cert of Excellence | AH TECK, JASON | Christ Church Grammar School | Claremont |
| 8 | Cert of Excellence | AITKEN, ELIZABETH CATHERINE | Perth Modern School | Subiaco |
| 9 | Cert of Excellence | AITKEN, EMILY KATE | Methodist Ladies College | Claremont |
| 10 | Cert of Excellence | AKL, JESSICA | Bunbury Catholic College | Bunbury |
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| 11 | Cert of Excellence | ALBERGHINI, JULIA MIKAELA | Methodist Ladies College | Claremont |
| 12 | Cert of Excellence | ALBERS, RACHAEL JANE | Ursula Frayne Catholic College | Victoria Park |
| 13 | Cert of Excellence | ALDERDICE, COURTNEY LEE | Lumen Christi College | Martin |
| 14 | Cert of Excellence | ALESSANDRINO, EMILY MARIA | Woodvale Secondary College | Woodvale |
| 15 | Cert of Excellence | ALEXANDER, ANEEKA | St Marys Anglican Girls School | Karrinyup |
| 16 | Cert of Excellence | ALEXI, JOANNA | Padbury Senior High School | Padbury |
| 17 | Cert of Excellence | ALFONSI, EMILY KATHRINE | Seton Catholic College | Samson |
| 18 | Cert of Excellence | ALI, MARLEY SHARAZ | Emmanuel Catholic College | Success |
| 19 | Cert of Excellence | ALLAN, BRETT CAMERON | Sacred Heart College | Sorrento |
| 20 | Cert of Excellence | ALLEN, EMILY FRANCES | Carine Senior High School | Carine |
| 21 | Cert of Excellence | AMARAL, NATHAN ROSS | Wesley College | South Perth |
| 22 | Cert of Excellence | ANDINATA, YONGKY | Applecross Senior High School | Ardross |
| 23 | Cert of Excellence | ANGKOLA, ELIZABETH | Sevenoaks Senior College | Cannington |
| 24 | Cert of Excellence | ANSELL, MEGAN ELISE | St Brigids College | Lesmurdie |
| 25 | Cert of Excellence | ARANCINI, NATASHA MARIE | Penrhos College | Como |
| 26 | Cert of Excellence | ARCHER, EMILY FRANCES | St Hildas Anglican School for Girls | Mosman Park |
| 27 | Cert of Excellence | ARDESHIRIAN, KUROUSH ALEXANDER | Wesley College | South Perth |
| 28 | Cert of Excellence | ARMITAGE, JESSE DAVID | Greenwood College | Greenwood |
| 29 | Cert of Excellence | ARMSTRONG, ALEXANDER JAMES | Prendiville Catholic College | Ocean Reef |
| 30 | Cert of Excellence | ARMSTRONG, BRODIE THOMAS | Bunbury Cathedral Grammar School | Gelorup |
| 31 | Cert of Excellence | ARMSTRONG, GUY PHILIP | Guildford Grammar School | Guildford |
| 32 | Cert of Excellence | ARMSTRONG, MORGAN | Applecross Senior High School | Ardross |
| 33 | Cert of Excellence | ARMSTRONG, SOPHIE ELIZABETH | St Stephens School Carramar | Tapping |
| 34 | Cert of Excellence | ARNOLD, IMOGEN LEE | Perth College | Mount Lawley |
| 35 | Cert of Excellence | ASHTON, JONATHON MARK | Aquinas College | Salter Point |
| 36 | Cert of Excellence | ATKINS, CHELSEA ENID | St Stephens School Duncraig | Duncraig |
| 37 | Cert of Excellence | ATKINSON, BRENTON DAVID | St Josephs College | Albany |
| 38 | Cert of Excellence | ATMAJA, ENRICO DHARMA | Aranmore Catholic College | Leederville |
| 39 | Cert of Excellence | AUSTIN, SHANII ROSE | Mount Lawley Senior High School | Mount Lawley |
| 40 | Cert of Excellence | AXTENS, NATHAN BRUCE | Willetton Senior High School | Willetton |
| 41 | Cert of Excellence | BAARS, LENA MARIE | St Marys Anglican Girls School | Karrinyup |
| 42 | Cert of Excellence | BAILEY, KALLA LOUISE | Santa Maria College | Attadale |
| 43 | Cert of Excellence | BAILEY, NICOLA DANIELLE | St Hildas Anglican School for Girls | Mosman Park |
| 44 | Cert of Excellence | BAKOVIC, ANTE | Melville Senior High School | Melville |
| 45 | Cert of Excellence | BALESTRA, JACINTA ELIA | Perth College | Mount Lawley |
| 46 | Cert of Excellence | BALHARRIE, IMOGEN ALEECE | Santa Maria College | Attadale |
| 47 | Cert of Excellence | BALL, SARAI ALYCIA | Belridge Secondary College | Beldon |
| 48 | Cert of Excellence | BAMFORD, OLIVIA MAREE | Busselton Senior High School | Busselton |
| 49 | Cert of Excellence | BARCINSKI, SAMUEL PHILIP | Scotch College | Swanbourne |
| 50 | Cert of Excellence | BARKER, SCOTT ANDREW | Armadale Senior High School | Armadale |