This report lists the winners of Certificates of Distinction and Certificates of Merit for 2014, along with the school that they attended.
These certificates are awarded to students who achieve at least 150 points (Certificate of Merit) or 190 points (Certificate of Distinction) across 20 year 11 and year 12 course units or equivalents, of which 10 are at year 12 level.
Formerly these awards were named Certificates of Commendation (2012-2015) or Certificates of Excellence (prior to 2012), and were based on achievements of at least 20 'A' grades in course units or equivalents.
| 1 | Cert of Commendation | ADAMS, NICOLE JAYNE | Kingsway Christian College | Darch |
| 2 | Cert of Commendation | ADAMS, WAYNE GERARD | Perth Modern School | Subiaco |
| 3 | Cert of Commendation | ADENIYI, ANUOLUWASUBOMI | Wesley College | South Perth |
| 4 | Cert of Commendation | AFIAT, BRANDON JOSHUA | Christ Church Grammar School | Claremont |
| 5 | Cert of Commendation | AGRELA, BRITNEY KAYLEE | Mindarie Senior College | Clarkson |
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| 6 | Cert of Commendation | AH-TIVE, SHALEAH THERESSA | John Paul College | Kalgoorlie |
| 7 | Cert of Commendation | ALLAN, JEFFERSON WILLIAM | Shenton College | Shenton Park |
| 8 | Cert of Commendation | ALLUM, TEGAN REBECCA | Kalamunda Senior High School | Kalamunda |
| 9 | Cert of Commendation | ALSOP, SAMUEL JACOB | Frederick Irwin Anglican School | Mandurah |
| 10 | Cert of Commendation | AMARAL, BRANDON | Wesley College | South Perth |
| 11 | Cert of Commendation | AMIDZIC, STEFANELA | St Hildas Anglican School for Girls | Mosman Park |
| 12 | Cert of Commendation | ANDREWS, NATALIE SUEMEI | Ursula Frayne Catholic College | Victoria Park |
| 13 | Cert of Commendation | ANIERE, NICOLA | Presbyterian Ladies College | Peppermint Grove |
| 14 | Cert of Commendation | ANTHONY, ERIN KATE | Corpus Christi College | Willetton |
| 15 | Cert of Commendation | BACOVIC, TARA | Mount Lawley Senior High School | Mount Lawley |
| 16 | Cert of Commendation | BAGWE, ISHA | Perth College | Mount Lawley |
| 17 | Cert of Commendation | BAJERAI, SH MOHAMMAD DIEN BIN SH HASSAN | Australian Islamic College Kewdale | Kewdale |
| 18 | Cert of Commendation | BAKER, ALEXANDER EDWARD | Woodvale Secondary College | Woodvale |
| 19 | Cert of Commendation | BALAJI, ARJUN | Perth Modern School | Subiaco |
| 20 | Cert of Commendation | BANKS, ELIZA CLAIRE | Santa Maria College | Melville |
| 21 | Cert of Commendation | BANTOCK, HARRISON JAMES | Scotch College | Claremont |
| 22 | Cert of Commendation | BARBETTI, MEGAN THERESE | Perth Modern School | Subiaco |
| 23 | Cert of Commendation | BARRETT, EMILY RUTH | Shenton College | Shenton Park |
| 24 | Cert of Commendation | BEERKENS, STEPHEN DANIEL | La Salle College | Midland |
| 25 | Cert of Commendation | BEGHO, JOSHUA NISHAN | Kennedy Baptist College | Bull Creek |