This report lists the winners of Certificates of Distinction and Certificates of Merit for 2007, along with the school that they attended.
These certificates are awarded to students who achieve at least 150 points (Certificate of Merit) or 190 points (Certificate of Distinction) across 20 year 11 and year 12 course units or equivalents, of which 10 are at year 12 level.
Formerly these awards were named Certificates of Commendation (2012-2015) or Certificates of Excellence (prior to 2012), and were based on achievements of at least 20 'A' grades in course units or equivalents.
| 1 | Cert of Excellence | ABEL, SAMUEL | Lesmurdie Senior High School | Lesmurdie |
| 2 | Cert of Excellence | ALKHATIB, LUMA | Duncraig Senior High School | Duncraig |
| 3 | Cert of Excellence | ALLEN, BENJAMIN | Carine Senior High School | Carine |
| 4 | Cert of Excellence | ALLEN, LEO | Guildford Grammar School | Guildford |
| 5 | Cert of Excellence | ALTMAN, NAOMI | Carmel School | Dianella |
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| 6 | Cert of Excellence | AMUDALAPALLI, SRAVYA | Penrhos College | Como |
| 7 | Cert of Excellence | ANDREWS, STEPHEN | Aquinas College | Salter Point |
| 8 | Cert of Excellence | ANGLISS, OLIVER | Christ Church Grammar School | Claremont |
| 9 | Cert of Excellence | ANTONIO, LUKE | Kolbe Catholic College | Rockingham |
| 10 | Cert of Excellence | APELDOORN, TAMARA | Darling Range Sports College | Forrestfield |
| 11 | Cert of Excellence | ARCHIBALD, LEON | Northam Senior High School | Northam |
| 12 | Cert of Excellence | ARENA, MICHAEL | Frederick Irwin Anglican School | Mandurah |
| 13 | Cert of Excellence | ASHMAN, SAMANTHA | Woodvale Secondary College | Woodvale |
| 14 | Cert of Excellence | ATMODJO, TACHELLA | Rossmoyne Senior High School | Rossmoyne |
| 15 | Cert of Excellence | AUSMA, KAGGEN | Albany Senior High School | Albany |
| 16 | Cert of Excellence | AVENT, MATTHEW | Corpus Christi College | Willetton |
| 17 | Cert of Excellence | AXFORD, LUKE | Willetton Senior High School | Willetton |
| 18 | Cert of Excellence | AYRE, MICHAEL | Bunbury Catholic College | Bunbury |
| 19 | Cert of Excellence | AZALIMI, MAHDI | Australian Islamic College Kewdale | Kewdale |
| 20 | Cert of Excellence | BABIC, STEPHANIE | St Brigids College | Lesmurdie |
| 21 | Cert of Excellence | BADENHORST, CLAIRE | Perth College | Mount Lawley |
| 22 | Cert of Excellence | BAGINI, ALEX | Chisholm Catholic College | Inglewood |
| 23 | Cert of Excellence | BALDOCK, MARINA | Governor Stirling Senior High School | Woodbridge |
| 24 | Cert of Excellence | BANCROFT, MELUKA | Busselton Senior High School | Busselton |
| 25 | Cert of Excellence | BANTUM, TAMIAH | Willetton Senior High School | Willetton |