This report lists the students who received a Governor of South Australia SACE Award or a Governor of South Australia Aboriginal Student SACE Award in 2021. These awards recognise overall excellence in the SACE.
Students can receive a Governor of South Australia SACE Award by achieving an A+ with merit in five year 12 subjects including the Research Project, or by demonstrating excellence in their SACE studies and in the SACE capabilities of communication, learning, personal development, citizenship and work.
Eligibility is based on student SACE results and school nominations.
| 1 | Gov of SA Aboriginal Student SACE Award | Henderson, Chloe | Salisbury High School | Salisbury North | |
| 2 | Gov of SA Excellence in Modified SACE Award | Baker, Kyle | Blackfriars Priory School | Prospect | |
| 3 | Gov of SA SACE Award | Alfred, Sebastian | Christian Brothers College | Adelaide | 99.7 |
| 4 | Gov of SA SACE Award | Ali, Muhammad | Thebarton Senior College | Torrensville | |
| 5 | Gov of SA SACE Award | Anchor, Caitlin | Kildare College | Holden Hill | 99.85 |
| 6 | Gov of SA SACE Award | Augustine, Manish | Rostrevor College | Woodforde | 98.25 |
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| 7 | Gov of SA SACE Award | Champion, Anna | Pulteney Grammar School | Adelaide | 99.55 |
| 8 | Gov of SA SACE Award | Di Cola, Lily | Cabra Dominican College | Cumberland Park | |
| 9 | Gov of SA SACE Award | Farrell, Lily | Loreto College | Marryatville | 99 |
| 10 | Gov of SA SACE Award | Frew, Thomas | Nazareth Catholic College | Flinders Park | 99.8 |
| 11 | Gov of SA SACE Award | Gregurev, Grace | Endeavour College | Mawson Lakes | 98.15 |
| 12 | Gov of SA SACE Award | Gunn, Katelin | Scotch College | Torrens Park | 88.9 |
| 13 | Gov of SA SACE Award | Henderson, Chloe | Salisbury High School | Salisbury North | |
| 14 | Gov of SA SACE Award | Hislop, Emma | Eynesbury Senior College | Adelaide | 99.4 |
| 15 | Gov of SA SACE Award | Jury, Daisy | Westminster School | Marion | |
| 16 | Gov of SA SACE Award | Kehagias, Georgia | Immanuel College | Novar Gardens | 99.05 |
| 17 | Gov of SA SACE Award | Lindblom, Zane | Westminster School | Marion | 96.25 |
| 18 | Gov of SA SACE Award | Lindner, Emily | Seymour College | Glen Osmond | 99.25 |
| 19 | Gov of SA SACE Award | Menadue, Keeley | Xavier College Gawler Belt Campus | Gawler Belt | 98.05 |
| 20 | Gov of SA SACE Award | Moss, Madeleine | Walford Anglican School for Girls | Hyde Park | 99.9 |
| 21 | Gov of SA SACE Award | Orsillo, Lillian | Sacred Heart College | Somerton Park | 98.25 |
| 22 | Gov of SA SACE Award | Page, Nikita | Wilderness School | Medindie | |
| 23 | Gov of SA SACE Award | Park, Gyum (Clive) | Pembroke School | Kensington Park | 99.95 |
| 24 | Gov of SA SACE Award | Ransom, Joel | St Johns Grammar School | Belair | |
| 25 | Gov of SA SACE Award | Roberts, Tayla | Streaky Bay Area School | Streaky Bay | 99.95 |
| 26 | Gov of SA SACE Award | Schutz, Holly | Pedare Christian College | Golden Grove | 98.55 |
| 27 | Gov of SA SACE Award | Scroop, Lucas | St Johns Grammar School | Belair | 99.95 |
| 28 | Gov of SA SACE Award | Vincin-Walker, Evelyn | Saint Ignatius College | Athelstone | |
| 29 | Gov of SA SACE Award | Whitbread, Cooper | Modbury High School | Modbury | 99.1 |
| 30 | Gov of SA SACE Award | Wight, Tess | Tenison Woods College | Mount Gambier | 95.45 |
| 31 | Gov of SA SACE Award | Wong, Cheri | St Peters Girls School | Stonyfell | 99.9 |