| 1862 | Bumpstead, Amy Joan | Luther College | Croydon Hills | Psychology | 41 |
| 1863 | Bumpstead, Amy Joan | Luther College | Croydon Hills | Legal Studies | 40 |
| 1864 | Bunawan, Rafael Rafka-Sulistio | St Francis Xavier College | Beaconsfield | English as an Additional Language | 41 |
| 1865 | Bungiriya, Isura Umayanga | Nossal High School | Berwick | Mathematical Methods | 45 |
| 1866 | Bungiriya, Isura Umayanga | Nossal High School | Berwick | Specialist Mathematics | 44 |
| 1867 | Bungiriya, Isura Umayanga | Nossal High School | Berwick | Physics | 42 |
| 1868 | Bunn, William Jack | St Bedes College | Mentone | English | 50 |
| 1869 | Bunn, William Jack | St Bedes College | Mentone | Geography | 50 |
| 1870 | Bunn, William Jack | St Bedes College | Mentone | Global Politics | 50 |
| 1871 | Bunn, William Jack | St Bedes College | Mentone | Legal Studies | 44 |
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| 1872 | Bunnage, Samuel Benjamin | Haileybury College | Keysborough | English | 46 |
| 1873 | Bunnage, Samuel Benjamin | Haileybury College | Keysborough | Languages: French | 40 |
| 1874 | Buntrock, Samantha | Berwick Secondary College | Berwick | English | 44 |
| 1875 | Bunyamin, Glenn Jonathan | Melbourne High School | South Yarra | Chemistry | 46 |
| 1876 | Bunyamin, Glenn Jonathan | Melbourne High School | South Yarra | Mathematical Methods | 44 |
| 1877 | Bunyamin, Glenn Jonathan | Melbourne High School | South Yarra | Physics | 43 |
| 1878 | Bunyamin, Glenn Jonathan | Melbourne High School | South Yarra | Specialist Mathematics | 41 |
| 1879 | Burchill, Renee Safira | Our Lady of Sion College | Box Hill | Legal Studies | 40 |
| 1880 | Burgess, Harry Thomas | Goulburn Valley Grammar School | Shepparton | Mathematical Methods | 43 |
| 1881 | Burgess, Harry Thomas | Goulburn Valley Grammar School | Shepparton | Physics | 42 |
| 1882 | Burgess, Harry Thomas | Goulburn Valley Grammar School | Shepparton | Specialist Mathematics | 40 |
| 1883 | Burgess, John Desmond | St Kevins College | Toorak | English | 50 |
| 1884 | Burgess, John Desmond | St Kevins College | Toorak | Theatre Studies | 44 |
| 1885 | Burgess, John Desmond | St Kevins College | Toorak | Literature | 42 |
| 1886 | Burgess, John Desmond | St Kevins College | Toorak | Further Mathematics | 40 |
| 1887 | Burgess, Kate Elizabeth | Lauriston Girls School | Armadale | Business Management | 44 |
| 1888 | Burgess, Riley John | Emmaus College | Vermont South | Business Management | 42 |
| 1889 | Burgess, Thomas Neale | Scotch College | Hawthorn | Further Mathematics | 43 |
| 1890 | Burgess-Hoar, Ruby Blanche | Geelong Grammar School | Corio | Media | 47 |
| 1891 | Burgess-Hoar, Ruby Blanche | Geelong Grammar School | Corio | English | 46 |
| 1892 | Burgess-Hoar, Ruby Blanche | Geelong Grammar School | Corio | Literature | 41 |
| 1893 | Burgoine, Emily Louise | Kilvington Grammar School | Ormond | Food Studies | 40 |
| 1894 | Buritica Monroy, Andres David | Scotch College | Hawthorn | Mathematical Methods | 50 |
| 1895 | Buritica Monroy, Andres David | Scotch College | Hawthorn | Economics | 41 |
| 1896 | Burke, Alice Grace | Haileybury Girls College | Keysborough | Further Mathematics | 49 |
| 1897 | Burke, Alice Grace | Haileybury Girls College | Keysborough | English | 41 |
| 1898 | Burke, Alice Grace | Haileybury Girls College | Keysborough | Physical Education | 41 |
| 1899 | Burke, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | Health and Human Development | 48 |
| 1900 | Burke, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | Business Management | 44 |
| 1901 | Burke, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | Dance | 44 |
| 1902 | Burke, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | English | 44 |
| 1903 | Burke, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | Further Mathematics | 40 |
| 1904 | Burke, Caitlin Joyce | Mentone Grammar School | Mentone | Physical Education | 47 |
| 1905 | Burke, Harvey James | St Bedes College | Mentone | Health and Human Development | 45 |
| 1906 | Burke, Harvey James | St Bedes College | Mentone | English | 40 |
| 1907 | Burke, Liam Shannon | St Kevins College | Toorak | English | 44 |
| 1908 | Burke, Liam Shannon | St Kevins College | Toorak | Further Mathematics | 43 |
| 1909 | Burke, Lucas William | Ballarat Grammar School | Wendouree | Music Performance | 43 |
| 1910 | Burleigh, Stephanie Rae | Our Lady of Sacred Heart College | Bentleigh | Product Design and Technology | 45 |
| 1911 | Burley, Angus | Caulfield Grammar School Caulfield | St Kilda East | Further Mathematics | 48 |