| 1925 | BURKE, Nicholas Kevin | Haileybury College | Keysborough | Accounting | 45 |
| 1926 | BURKE, Nicholas Kevin | Haileybury College | Keysborough | Business Management | 43 |
| 1927 | BURKE, Oliver Miller | Xavier College | Kew | Studio Arts | 45 |
| 1928 | BURKE, Oliver Miller | Xavier College | Kew | English | 43 |
| 1929 | BURNELL, Chiara Antonietta | Templestowe College | Templestowe Lower | Psychology | 40 |
| 1930 | BURNELL, Lucy Ailsa Rose | Firbank Grammar School | Brighton | English | 41 |
| 1931 | BURNELL, Lucy Ailsa Rose | Firbank Grammar School | Brighton | Health and Human Development | 41 |
| 1932 | BURNES, Ruby Bernadette | Genazzano F.C.J. College | Kew | Art | 41 |
| 1933 | BURNETT, Emily Louise | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Theatre Studies | 44 |
| 1934 | BURNETT, Emily Louise | Caulfield Grammar School Wheelers Hill | Wheelers Hill | English | 43 |
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| 1935 | BURNETT, Thomas Graeme | Ballarat Grammar School | Wendouree | English Language | 46 |
| 1936 | BURNETT, Thomas Graeme | Ballarat Grammar School | Wendouree | Physics | 44 |
| 1937 | BURNETT, Thomas Graeme | Ballarat Grammar School | Wendouree | Specialist Mathematics | 43 |
| 1938 | BURNETT, Thomas Graeme | Ballarat Grammar School | Wendouree | Chemistry | 40 |
| 1939 | BURNHAM, Danielle Traleen | Padua College | Mornington | Outdoor and Environmental Studies | 41 |
| 1940 | BURNS BRADLEY, Sienna Grace | Melbourne Girls College | Richmond | Legal Studies | 45 |
| 1941 | BURNS, Angus George | McClelland Secondary College | Frankston | English | 40 |
| 1942 | BURNS, Blair William | Huntingtower School | Mount Waverley | Informatics | 45 |
| 1943 | BURNS, Brianna Mei | Beaconhills College Pakenham | Pakenham | History: Revolutions | 41 |
| 1944 | BURNS, Brianna Mei | Beaconhills College Pakenham | Pakenham | English | 40 |
| 1945 | BURNS, Campbell Regan | St Josephs College Geelong | Newtown | Further Mathematics | 43 |
| 1946 | BURNS, Emma Catherine | Sacred Heart College Geelong | Newtown | Outdoor and Environmental Studies | 41 |
| 1947 | BURNS, Jonathan James | St Josephs College Geelong | Newtown | Legal Studies | 44 |
| 1948 | BURNS, Jonathan James | St Josephs College Geelong | Newtown | English | 41 |
| 1949 | BURNS, Maisie Emma-Rose | Sunbury Downs Secondary College | Sunbury | Studio Arts | 40 |
| 1950 | BURNS, Riley | Loreto Mandeville Hall | Toorak | Physical Education | 47 |
| 1951 | BURNS, Riley Finn | Point Cook Senior Secondary College | Point Cook | Software Development | 42 |
| 1952 | BURNS, Tegan | Loreto Mandeville Hall | Toorak | English | 50 |
| 1953 | BURNS, Tegan | Loreto Mandeville Hall | Toorak | Physical Education | 50 |
| 1954 | BURNS, Tegan | Loreto Mandeville Hall | Toorak | Chemistry | 45 |
| 1955 | BURNS, Tegan | Loreto Mandeville Hall | Toorak | Physics | 42 |
| 1956 | BURNS, Tegan | Loreto Mandeville Hall | Toorak | Specialist Mathematics | 40 |
| 1957 | BURR, Benjamin | Eltham College of Education | Research | Studio Arts | 40 |
| 1958 | BURRAGE, Helena Strachan | Northcote High School | Northcote | English | 40 |
| 1959 | BURRAGE, Helena Strachan | Northcote High School | Northcote | Psychology | 40 |
| 1960 | BURROWS, Anna Jane | Viewbank College | Viewbank | Further Mathematics | 41 |
| 1961 | BURROWS, Camilla Dalia | The King David School | Armadale | Religion and Society | 42 |
| 1962 | BURSILL, Mason Stuart | St Margarets Berwick Grammar Officer Campus | Officer | Physical Education | 43 |
| 1963 | BURSTIN, Georgia Halina | The King David School | Armadale | Physical Education | 43 |
| 1964 | BURSTON, Georgia | Bacchus Marsh Grammar | Bacchus Marsh | Business Management | 45 |
| 1965 | BURSZTYN, Jasmine Isabella | Bialik College | Hawthorn | Legal Studies | 49 |
| 1966 | BURSZTYN, Jasmine Isabella | Bialik College | Hawthorn | English | 44 |
| 1967 | BURSZTYN, Jasmine Isabella | Bialik College | Hawthorn | Accounting | 41 |
| 1968 | BURSZTYN, Joshua Jonathan | Bialik College | Hawthorn | Mathematical Methods | 43 |
| 1969 | BURT, Edmund Ralph | Brighton Grammar School | Brighton | English | 46 |
| 1970 | BURT, Thomas Gerald | Xavier College | Kew | English | 44 |
| 1971 | BURT, Thomas Gerald | Xavier College | Kew | Further Mathematics | 41 |
| 1972 | BURT, Thomas Gerald | Xavier College | Kew | Visual Communication Design | 40 |
| 1973 | BURTON, Conroy Allen John | Ivanhoe Grammar School Plenty | Doreen | Software Development | 40 |
| 1974 | BURTON, Jade Crystal | Melton Secondary College | Melton | Studio Arts | 40 |