| 1920 | BUNNAGE, Tristan | Box Hill High School | Box Hill | Physics | 42 |
| 1921 | BUNSTON, Zachary Mark | Trinity Grammar School | Kew | Art | 41 |
| 1922 | BUNTINE, Annie Rose | Peninsula Grammar | Mount Eliza | Business Management | 42 |
| 1923 | BUNTING, Melina Vittorina | Sacred Heart College Geelong | Newtown | English | 42 |
| 1924 | BUNYAMIN, Kaitlyn Angela | MacRobertson Girls High School | Melbourne | Accounting | 47 |
| 1925 | BUNYAMIN, Kaitlyn Angela | MacRobertson Girls High School | Melbourne | Legal Studies | 43 |
| 1926 | BUONOMO, Ross Leonard | Goulburn Valley Grammar School | Shepparton | Further Mathematics | 43 |
| 1927 | BURCHETT, Linda Jane | Yarra Valley Grammar School | Ringwood | Literature | 46 |
| 1928 | BURCHETT, Linda Jane | Yarra Valley Grammar School | Ringwood | Languages: French | 44 |
| 1929 | BURCHETT, Linda Jane | Yarra Valley Grammar School | Ringwood | Biology | 43 |
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| 1930 | BURCHETT, Linda Jane | Yarra Valley Grammar School | Ringwood | Chemistry | 40 |
| 1931 | BURENKOVA, Ana Svetlana | Elwood College | Elwood | English | 45 |
| 1932 | BURFORD, Monika Barbara | Padua College | Mornington | Chemistry | 42 |
| 1933 | BURFORD, Monika Barbara | Padua College | Mornington | Physics | 41 |
| 1934 | BURGE, Sarah Kate | Geelong High School | East Geelong | Psychology | 46 |
| 1935 | BURGER, Sarah Jacqueline | Fintona Girls School | Balwyn | English | 44 |
| 1936 | BURGER, Sarah Jacqueline | Fintona Girls School | Balwyn | Languages: French | 44 |
| 1937 | BURGER, Sarah Jacqueline | Fintona Girls School | Balwyn | Chemistry | 41 |
| 1938 | BURGESS, Aleisha Nicole | Yarra Valley Grammar School | Ringwood | Business Management | 44 |
| 1939 | BURGESS, Anthea Elizabeth | Sacred Heart Girls College | Hughesdale | English | 40 |
| 1940 | BURGESS, Jack | Kardinia International College | Bell Post Hill | Further Mathematics | 41 |
| 1941 | BURGESS, Madeleine Louise | Fintona Girls School | Balwyn | Psychology | 40 |
| 1942 | BURGESS, Michael John | St Kevins College | Toorak | English | 50 |
| 1943 | BURGESS, Michael John | St Kevins College | Toorak | Physics | 43 |
| 1944 | BURGESS, Michael John | St Kevins College | Toorak | Business Management | 42 |
| 1945 | BURGESS, Michael John | St Kevins College | Toorak | Specialist Mathematics | 42 |
| 1946 | BURGESS, Mitchell Anthony | St Kevins College | Toorak | Business Management | 45 |
| 1947 | BURGESS, Samantha Jean | Lauriston Girls School | Armadale | English | 40 |
| 1948 | BURGESS, Samantha Jean | Lauriston Girls School | Armadale | Media | 40 |
| 1949 | BURKE, Eamon William | Yarra Valley Grammar School | Ringwood | Further Mathematics | 47 |
| 1950 | BURKE, Eamon William | Yarra Valley Grammar School | Ringwood | Business Management | 44 |
| 1951 | BURKE, Elizabeth Kathleen | Korowa Anglican Girls School | Glen Iris | English | 42 |
| 1952 | BURKE, Jack | Whitefriars College | Donvale | Australian History | 44 |
| 1953 | BURKE, Jack | Whitefriars College | Donvale | Business Management | 41 |
| 1954 | BURKE, Jack | Whitefriars College | Donvale | English | 41 |
| 1955 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | Mathematical Methods (CAS) | 50 |
| 1956 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | Physics | 50 |
| 1957 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | Chemistry | 49 |
| 1958 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | Specialist Mathematics | 47 |
| 1959 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | English | 42 |
| 1960 | BURKE, Kelvin Carl | Penleigh and Essendon Grammar School | Keilor East | Languages: French | 40 |
| 1961 | BURKE, Lachlan Myles | Trinity Grammar School | Kew | Business Management | 44 |
| 1962 | BURKE, Lachlan Myles | Trinity Grammar School | Kew | English | 44 |
| 1963 | BURKE, Ruby Mae | Star of the Sea College | Brighton | Further Mathematics | 41 |
| 1964 | BURKE, Ruby Mae | Star of the Sea College | Brighton | English | 40 |
| 1965 | BURKE, Sheldon Patrick | Catholic College Bendigo | Bendigo | Outdoor and Environmental Studies | 40 |
| 1966 | BURKE, Yasmin Estelle | Wesley College St Kilda Rd | Melbourne | Psychology | 40 |
| 1967 | BURKHARDT, Matthew James | Westbourne Grammar School | Truganina | Biology | 43 |
| 1968 | BURL, Corey Francis | St Bedes College | Mentone | Health and Human Development | 42 |
| 1969 | BURMEISTER, Harry Timothy | Wesley College St Kilda Rd | Melbourne | Studio Arts | 42 |