| 2003 | Bryce, Jonathan | The King David School | Armadale | Physical Education | 40 |
| 2004 | Bryce, Jonathan | The King David School | Armadale | Physics | 40 |
| 2005 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Geography | 44 |
| 2006 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Physical Education | 42 |
| 2007 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Biology | 40 |
| 2008 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Further Mathematics | 40 |
| 2009 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | English Language | 42 |
| 2010 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | Further Mathematics | 41 |
| 2011 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | Biology | 40 |
| 2012 | Brydon, Christopher | Glen Waverley Secondary College | Glen Waverley | International Studies | 43 |
| |
|||||
| 2013 | Brydon, Christopher | Glen Waverley Secondary College | Glen Waverley | Economics | 40 |
| 2014 | Brydon, Christopher | Glen Waverley Secondary College | Glen Waverley | English | 40 |
| 2015 | Bu, Kenjoe | Wheelers Hill Secondary College | Wheelers Hill | English | 44 |
| 2016 | Bu, Kenjoe | Wheelers Hill Secondary College | Wheelers Hill | Further Mathematics | 44 |
| 2017 | Buchanan, Adam | Macleod College | Macleod | Further Mathematics | 42 |
| 2018 | Buchanan, Kyle | Camberwell High School | Canterbury | Physical Education | 43 |
| 2019 | Buchanan, Meghan | Brauer College | Warrnambool | Outdoor and Environmental Studies | 44 |
| 2020 | Buchanan, Meghan | Brauer College | Warrnambool | Visual Communication Design | 43 |
| 2021 | Buchanan, Roberta | Genazzano F.C.J. College | Kew | English | 42 |
| 2022 | Buchanan, Roberta | Genazzano F.C.J. College | Kew | Legal Studies | 40 |
| 2023 | Buchholz, Kali | Berwick Secondary College | Berwick | Further Mathematics | 45 |
| 2024 | Buchholz, Kali | Berwick Secondary College | Berwick | Chemistry | 40 |
| 2025 | Buck, Michael | St Bedes College | Mentone | English Language | 49 |
| 2026 | Buck, Michael | St Bedes College | Mentone | History: Revolutions | 46 |
| 2027 | Buck, Michael | St Bedes College | Mentone | Languages: French | 45 |
| 2028 | Buckham, Dominic | Princes Hill Secondary College | Princes Hill | Media | 40 |
| 2029 | Buckley, Amy | Salesian College Sunbury | Sunbury | Health and Human Development | 40 |
| 2030 | Buckley, Lachlan | Yarra Valley Grammar School | Ringwood | Further Mathematics | 45 |
| 2031 | Budden, Tessa | Our Lady of Mercy College | Heidelberg | Food and Technology | 42 |
| 2032 | Budge, Emily | Aitken College | Greenvale | Accounting | 42 |
| 2033 | Budilov, Katerina | Firbank Grammar School | Brighton | International Studies | 43 |
| 2034 | Budilov, Katerina | Firbank Grammar School | Brighton | English | 40 |
| 2035 | Budin, Alyssa | Wesley College St Kilda Rd | Melbourne | English | 44 |
| 2036 | Budin, Alyssa | Wesley College St Kilda Rd | Melbourne | Biology | 42 |
| 2037 | Budin, Alyssa | Wesley College St Kilda Rd | Melbourne | Psychology | 40 |
| 2038 | Buenemann, Paige | Ivanhoe Girls Grammar School | Ivanhoe | Australian History | 44 |
| 2039 | Bugden, Katelyn | Damascus College | Mount Clear | Physical Education | 43 |
| 2040 | Bugeja, Nicole | Emmaus College | Vermont South | Art | 42 |
| 2041 | Bugeja, Nicole | Emmaus College | Vermont South | Design and Technology | 42 |
| 2042 | Bugg, Elyssia | Woodleigh School | Langwarrin South | Literature | 45 |
| 2043 | Bugg, Elyssia | Woodleigh School | Langwarrin South | Media | 45 |
| 2044 | Bugg, Elyssia | Woodleigh School | Langwarrin South | English | 43 |
| 2045 | Bugg, Elyssia | Woodleigh School | Langwarrin South | Art | 40 |
| 2046 | Bugg, Elyssia | Woodleigh School | Langwarrin South | History: Revolutions | 40 |
| 2047 | Buglass, Leigh | Yarra Valley Grammar School | Ringwood | Further Mathematics | 48 |
| 2048 | Buglass, Leigh | Yarra Valley Grammar School | Ringwood | Interactive Digital Media (VCE VET) | 40 |
| 2049 | Buhagiar, Jaymie | Ave Maria College | Aberfeldie | Visual Communication Design | 40 |
| 2050 | Buhariwala, Carl | Camberwell Grammar School | Canterbury | Legal Studies | 46 |
| 2051 | Buhariwala, Carl | Camberwell Grammar School | Canterbury | Economics | 44 |
| 2052 | Buhariwala, Carl | Camberwell Grammar School | Canterbury | English | 42 |