| 1964 | Browning, Rowan | Koonung Secondary College | Mont Albert North | Mathematical Methods (CAS) | 41 |
| 1965 | Brownlow, Sian | Caulfield Grammar School Caulfield | St Kilda East | Mathematical Methods (CAS) | 41 |
| 1966 | Brownstein, Daniel | Kardinia International College | Bell Post Hill | Biology | 45 |
| 1967 | Brownstein, Daniel | Kardinia International College | Bell Post Hill | English | 41 |
| 1968 | Brownstein, Daniel | Kardinia International College | Bell Post Hill | Chemistry | 40 |
| 1969 | Bruce, Hilary | Chairo Christian School Drouin | Drouin | Visual Communication Design | 46 |
| 1970 | Bruce, Hilary | Chairo Christian School Drouin | Drouin | Physical Education | 42 |
| 1971 | Bruce, Hilary | Chairo Christian School Drouin | Drouin | English | 41 |
| 1972 | Bruce, Molly | Toorak College | Mount Eliza | Biology | 44 |
| 1973 | Bruce, Molly | Toorak College | Mount Eliza | Literature | 41 |
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| 1974 | Bruce, Molly | Toorak College | Mount Eliza | English | 40 |
| 1975 | Bruce, Renee | Mordialloc College | Mordialloc | Physical Education | 43 |
| 1976 | Bruckmann, Max | Ballarat Grammar School | Wendouree | Music Technical Production (VCE VET) | 41 |
| 1977 | Brugliera, Carla | Strathcona Girls Grammar School | Canterbury | Physical Education | 43 |
| 1978 | Brugman, Daniel | St Josephs College Geelong | Newtown | Psychology | 40 |
| 1979 | Brukner, William | Wesley College St Kilda Rd | Melbourne | English | 42 |
| 1980 | Brumley, Nathan | Peninsula Grammar | Mount Eliza | History: Revolutions | 45 |
| 1981 | Brumley, Nathan | Peninsula Grammar | Mount Eliza | English | 43 |
| 1982 | Brumley, Nathan | Peninsula Grammar | Mount Eliza | Legal Studies | 40 |
| 1983 | Brunda, Albert | Blackburn High School | Blackburn | Interactive Digital Media (VCE VET) | 45 |
| 1984 | Brunda, Albert | Blackburn High School | Blackburn | Further Mathematics | 40 |
| 1985 | Brunetti, Madison | Our Lady of Mercy College | Heidelberg | Legal Studies | 45 |
| 1986 | Brunetti, Madison | Our Lady of Mercy College | Heidelberg | Business Management | 43 |
| 1987 | Brunetti, Madison | Our Lady of Mercy College | Heidelberg | Food and Technology | 41 |
| 1988 | Bruning, Laura | Balwyn High School | Balwyn North | Food and Technology | 41 |
| 1989 | Bruno, Matthew | St Monicas College | Epping | English | 41 |
| 1990 | Brunt, Brodie | Catholic College Sale | Sale | Sport and Recreation (VCE VET) | 40 |
| 1991 | Brunton, Alana | Methodist Ladies College | Kew | Business Management | 42 |
| 1992 | Brunton, Alana | Methodist Ladies College | Kew | Visual Communication Design | 42 |
| 1993 | Brunton, Erin | Kardinia International College | Bell Post Hill | Further Mathematics | 43 |
| 1994 | Brusamarello, Courtney | Newhaven College | Rhyll | Biology | 40 |
| 1995 | Brush, Melissa | Viewbank College | Viewbank | English | 43 |
| 1996 | Brush, Melissa | Viewbank College | Viewbank | Literature | 42 |
| 1997 | Brush, Melissa | Viewbank College | Viewbank | Physics | 41 |
| 1998 | Bryant, Bjorn | Donvale Christian College | Donvale | Languages: German | 46 |
| 1999 | Bryant-Macdonald, Jessica | Camberwell High School | Canterbury | Psychology | 42 |
| 2000 | Bryant-Macdonald, Jessica | Camberwell High School | Canterbury | Drama | 40 |
| 2001 | Bryce, Colby | Warracknabeal Secondary College | Warracknabeal | Health and Human Development | 40 |
| 2002 | Bryce, Jonathan | The King David School | Armadale | Health and Human Development | 42 |
| 2003 | Bryce, Jonathan | The King David School | Armadale | Physical Education | 40 |
| 2004 | Bryce, Jonathan | The King David School | Armadale | Physics | 40 |
| 2005 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Geography | 44 |
| 2006 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Physical Education | 42 |
| 2007 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Biology | 40 |
| 2008 | Bryce, Patrick | Ballarat Clarendon College | Ballarat | Further Mathematics | 40 |
| 2009 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | English Language | 42 |
| 2010 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | Further Mathematics | 41 |
| 2011 | Brydges, Danielle | MacRobertson Girls High School | Melbourne | Biology | 40 |
| 2012 | Brydon, Christopher | Glen Waverley Secondary College | Glen Waverley | International Studies | 43 |
| 2013 | Brydon, Christopher | Glen Waverley Secondary College | Glen Waverley | Economics | 40 |