| 1884 | Brownstein, Adam | Wangaratta High School | Wangaratta | Biology | 48 |
| 1885 | Brownstein, Rosemary | Goulburn Valley Grammar School | Shepparton | Industry and Enterprise | 43 |
| 1886 | Bruccoleri, Alicia | Luther College | Croydon Hills | Business Management | 41 |
| 1887 | Bruccoleri, Alicia | Luther College | Croydon Hills | English | 40 |
| 1888 | Bruce, Ella | Siena College | Camberwell | Design and Technology | 41 |
| 1889 | Bruce, Ella | Siena College | Camberwell | Studio Arts | 41 |
| 1890 | Bruce, Lauren | Strathmore Secondary College | Strathmore | Design and Technology | 40 |
| 1891 | Bruce, Matthew | Mazenod College | Mulgrave | Business Management | 41 |
| 1892 | Bruce, Rachael | Chairo Christian School Drouin | Drouin | English | 41 |
| 1893 | Bruch, Dannielle | Mornington Secondary College | Mornington | Food and Technology | 43 |
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| 1894 | Bruch, Dustin | Mount Scopus Memorial College | Burwood | Further Mathematics | 45 |
| 1895 | Bruders, Ashleigh | Beaconhills College Berwick | Berwick | Business Management | 45 |
| 1896 | Bruders, Ashleigh | Beaconhills College Berwick | Berwick | Legal Studies | 44 |
| 1897 | Bruders, Ashleigh | Beaconhills College Berwick | Berwick | Literature | 41 |
| 1898 | Bruerton, Jessica | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Physical Education | 47 |
| 1899 | Bruerton, Jessica | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Psychology | 45 |
| 1900 | Bruerton, Jessica | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Further Mathematics | 44 |
| 1901 | Bruerton, Jessica | Caulfield Grammar School Wheelers Hill | Wheelers Hill | English | 42 |
| 1902 | Brugliera, Giulia | Strathcona Girls Grammar School | Canterbury | Further Mathematics | 48 |
| 1903 | Brugliera, Giulia | Strathcona Girls Grammar School | Canterbury | English | 45 |
| 1904 | Brugliera, Giulia | Strathcona Girls Grammar School | Canterbury | Languages: Italian | 40 |
| 1905 | Brugman, Cullen | St Josephs College Geelong | Newtown | Further Mathematics | 42 |
| 1906 | Brugmans, Renee | Yarra Hills Secondary College Mooroolbark | Mooroolbark | Outdoor and Environmental Studies | 40 |
| 1907 | Brummell, Laura | Luther College | Croydon Hills | Psychology | 42 |
| 1908 | Brunacci, Naomi | Lara Secondary College | Lara | Health and Human Development | 42 |
| 1909 | Brunton, Sarah | Kardinia International College | Bell Post Hill | Further Mathematics | 44 |
| 1910 | Brunton, Sarah | Kardinia International College | Bell Post Hill | Accounting | 40 |
| 1911 | Brusco, Adele | Sacre Coeur | Glen Iris | IT Applications | 43 |
| 1912 | Bryan, Sarah | Box Hill High School | Box Hill | Psychology | 46 |
| 1913 | Bryan, Sarah | Box Hill High School | Box Hill | English | 44 |
| 1914 | Bryan, Sarah | Box Hill High School | Box Hill | Further Mathematics | 42 |
| 1915 | Bryant, Saskia | Donvale Christian College | Donvale | Psychology | 40 |
| 1916 | Bryce, Stephanie | The King David School | Armadale | Health and Human Development | 43 |
| 1917 | Bryce, Stephanie | The King David School | Armadale | Legal Studies | 42 |
| 1918 | Bryce, Stephanie | The King David School | Armadale | English | 41 |
| 1919 | Bryceson, Christopher | St Bernards College | Essendon | Accounting | 49 |
| 1920 | Bryceson, Christopher | St Bernards College | Essendon | Physical Education | 48 |
| 1921 | Bryceson, Christopher | St Bernards College | Essendon | Further Mathematics | 44 |
| 1922 | Bryl-Tyquin, John | Eltham College of Education | Research | Music (VCE VET) | 43 |
| 1923 | Brzica, Iva | Viewbank College | Viewbank | English | 44 |
| 1924 | Brzica, Iva | Viewbank College | Viewbank | Health and Human Development | 44 |
| 1925 | Buasuwan, Wanthip | Sacred Heart College Geelong | Newtown | Studio Arts | 42 |
| 1926 | Bubonya, Melisa | Sunbury College | Sunbury | Economics | 50 |
| 1927 | Bubonya, Melisa | Sunbury College | Sunbury | Accounting | 47 |
| 1928 | Bubonya, Melisa | Sunbury College | Sunbury | IT Applications | 45 |
| 1929 | Bucello, Christopher | Mary MacKillop Catholic College | Leongatha | Physical Education | 40 |
| 1930 | Buchanan, Alice | Brauer College | Warrnambool | Health and Human Development | 43 |
| 1931 | Buchanan, Edward | Melbourne Grammar School | Melbourne | English | 43 |
| 1932 | Buchanan, James | Goulburn Valley Grammar School | Shepparton | Further Mathematics | 43 |
| 1933 | Buchanan, Kelsey | Belmont High School | Belmont | Psychology | 44 |