| 1952 | Bruce, Daniel | Gisborne Secondary College | Gisborne | Further Mathematics | 43 |
| 1953 | Bruce, Kelly | Sacred Heart Girls College | Hughesdale | Australian History | 49 |
| 1954 | Bruce, Kelly | Sacred Heart Girls College | Hughesdale | Media | 46 |
| 1955 | Bruce, Meaghan | Marist Sion College | Warragul | History: Revolutions | 41 |
| 1956 | Bruce, Seona | Emmaus College | Vermont South | English | 44 |
| 1957 | Bruch, Cortney | Mount Scopus Memorial College | Burwood | Religion and Society | 44 |
| 1958 | Bruckard, Simon | Melbourne High School | South Yarra | Music Group Performance | 50 |
| 1959 | Bruckard, Simon | Melbourne High School | South Yarra | Languages: Japanese Second Language | 40 |
| 1960 | Brukner, Joseph | Melbourne High School | South Yarra | English | 42 |
| 1961 | Brukner, Joseph | Melbourne High School | South Yarra | Further Mathematics | 42 |
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| 1962 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Art | 46 |
| 1963 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | English | 44 |
| 1964 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Further Mathematics | 43 |
| 1965 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Health and Human Development | 42 |
| 1966 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Biology | 40 |
| 1967 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | English | 45 |
| 1968 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | Literature | 43 |
| 1969 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | Psychology | 43 |
| 1970 | Brumley, Kyle | Emmanuel College Warrnambool | Warrnambool | Further Mathematics | 42 |
| 1971 | Brumley, Lauren | Toorak College | Mount Eliza | Visual Communication Design | 50 |
| 1972 | Brumley, Lauren | Toorak College | Mount Eliza | Art | 48 |
| 1973 | Brumley, Lauren | Toorak College | Mount Eliza | English | 43 |
| 1974 | Brumley, Lauren | Toorak College | Mount Eliza | Further Mathematics | 42 |
| 1975 | Brun, Nicholas | Goulburn Valley Grammar School | Shepparton | IT Applications | 40 |
| 1976 | Bruni, Kristy | Kyneton High School | Kyneton | Food and Technology | 42 |
| 1977 | Bruns, Emma | Cohuna Secondary College | Cohuna | Physical Education | 45 |
| 1978 | Bruns, Kirsty | Charlton College | Charlton | Business Management | 43 |
| 1979 | Bruns, Kirsty | Charlton College | Charlton | Health and Human Development | 42 |
| 1980 | Bruns, Kirsty | Charlton College | Charlton | Accounting | 40 |
| 1981 | Brunton, Sarah | Pascoe Vale Girls Secondary College | Pascoe Vale | Media | 42 |
| 1982 | Brush, Stephanie | Werribee Secondary College | Werribee | History: Revolutions | 40 |
| 1983 | Brushett, Kaela | Faye Johnson-Ross School of Dance | Bentleigh East | Dance | 43 |
| 1984 | Bryan, Claire | Girton Grammar School | Bendigo | Design and Technology | 44 |
| 1985 | Bryan, Danielle | Nazareth College | Noble Park North | Health and Human Development | 41 |
| 1986 | Bryan, Elizabeth | Melbourne Girls College | Richmond | Outdoor and Environmental Studies | 47 |
| 1987 | Bryan, Sean | Flinders Christian Community College Tyabb | Tyabb | Drama | 43 |
| 1988 | Bryan, Sean | Flinders Christian Community College Tyabb | Tyabb | English | 40 |
| 1989 | Bryant, Alastair | Haileybury College | Keysborough | Literature | 40 |
| 1990 | Bryant, Sven | Donvale Christian College | Donvale | Languages: German | 50 |
| 1991 | Bryde, Lauren | Ashwood High School | Ashwood | Further Mathematics | 40 |
| 1992 | Bryden, Tyla | Ballarat Clarendon College | Ballarat | Psychology | 40 |
| 1993 | Brydon, Megan | Mentone Girls Grammar School | Mentone | English | 47 |
| 1994 | Brydon, Megan | Mentone Girls Grammar School | Mentone | Further Mathematics | 43 |
| 1995 | Brydon, Megan | Mentone Girls Grammar School | Mentone | Business Management | 42 |
| 1996 | Brydon, Megan | Mentone Girls Grammar School | Mentone | History: Revolutions | 40 |
| 1997 | Bubb, Jane | St Catherines School | Toorak | Accounting | 40 |
| 1998 | Bubniw, Andrew | Penleigh and Essendon Grammar School | Keilor East | English | 43 |
| 1999 | Buccheri, Lisa | MacKillop Catholic Regional College | Werribee | Design and Technology | 40 |
| 2000 | Bucciarelli, Adrian | Overnewton Anglican College | Keilor | Accounting | 41 |
| 2001 | Bucciarelli, Adrian | Overnewton Anglican College | Keilor | Business Management | 40 |