| 1922 | Brownbill, Lisa | Canterbury Girls Secondary College | Canterbury | Studio Arts | 43 |
| 1923 | Browne, Dannielle | Melton Secondary College | Melton | Psychology | 40 |
| 1924 | Browne, Emma | Eltham College of Education | Research | English | 46 |
| 1925 | Browne, Emma | Eltham College of Education | Research | Literature | 40 |
| 1926 | Browne, Fergus | Xavier College | Kew | Texts and Traditions | 40 |
| 1927 | Browne, Gemma | Santa Maria College | Northcote | Legal Studies | 40 |
| 1928 | Browne, Georgiana | Girton Grammar School | Bendigo | Dance | 42 |
| 1929 | Browne, Georgiana | Girton Grammar School | Bendigo | Languages: French | 40 |
| 1930 | Browne, Laura | Eltham College of Education | Research | English | 48 |
| 1931 | Browne, Laura | Eltham College of Education | Research | International Studies | 46 |
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| 1932 | Browne, Laura | Eltham College of Education | Research | Media | 45 |
| 1933 | Browne, Lucy | Williamstown High School | Williamstown | Psychology | 46 |
| 1934 | Browne, Lucy | Williamstown High School | Williamstown | English | 41 |
| 1935 | Browne, Natalie | St Michaels Grammar School | St Kilda | Studio Arts | 48 |
| 1936 | Browne, Natalie | St Michaels Grammar School | St Kilda | History: Revolutions | 45 |
| 1937 | Browne, Natalie | St Michaels Grammar School | St Kilda | Legal Studies | 42 |
| 1938 | Browne, Sarah | Caulfield Grammar School Caulfield | St Kilda East | Psychology | 42 |
| 1939 | Browne, Tessa | Notre Dame College | Shepparton | English | 42 |
| 1940 | Browne, Thomas | Eltham College of Education | Research | Media | 46 |
| 1941 | Browne, Thomas | Eltham College of Education | Research | English | 43 |
| 1942 | Browne, Thomas | Eltham College of Education | Research | Studio Arts | 43 |
| 1943 | Brownell, Sarah | Methodist Ladies College | Kew | Sport and Recreation (VCE VET) | 43 |
| 1944 | Brownstein, Emily | Canterbury Girls Secondary College | Canterbury | Psychology | 47 |
| 1945 | Brownstein, Sarah | Goulburn Valley Grammar School | Shepparton | Languages: Indonesian Second Language | 44 |
| 1946 | Brozgul, Berta | Victorian College of the Arts Secondary School | Southbank | Music Solo Performance | 46 |
| 1947 | Brozgul, Berta | Victorian College of the Arts Secondary School | Southbank | Languages: French | 41 |
| 1948 | Brozgul, Berta | Victorian College of the Arts Secondary School | Southbank | Literature | 41 |
| 1949 | Brozgul, Misty | MacRobertson Girls High School | Melbourne | Literature | 48 |
| 1950 | Brozgul, Misty | MacRobertson Girls High School | Melbourne | International Studies | 46 |
| 1951 | Brozgul, Misty | MacRobertson Girls High School | Melbourne | Philosophy | 46 |
| 1952 | Bruce, Daniel | Gisborne Secondary College | Gisborne | Further Mathematics | 43 |
| 1953 | Bruce, Kelly | Sacred Heart Girls College | Hughesdale | Australian History | 49 |
| 1954 | Bruce, Kelly | Sacred Heart Girls College | Hughesdale | Media | 46 |
| 1955 | Bruce, Meaghan | Marist Sion College | Warragul | History: Revolutions | 41 |
| 1956 | Bruce, Seona | Emmaus College | Vermont South | English | 44 |
| 1957 | Bruch, Cortney | Mount Scopus Memorial College | Burwood | Religion and Society | 44 |
| 1958 | Bruckard, Simon | Melbourne High School | South Yarra | Music Group Performance | 50 |
| 1959 | Bruckard, Simon | Melbourne High School | South Yarra | Languages: Japanese Second Language | 40 |
| 1960 | Brukner, Joseph | Melbourne High School | South Yarra | English | 42 |
| 1961 | Brukner, Joseph | Melbourne High School | South Yarra | Further Mathematics | 42 |
| 1962 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Art | 46 |
| 1963 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | English | 44 |
| 1964 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Further Mathematics | 43 |
| 1965 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Health and Human Development | 42 |
| 1966 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Biology | 40 |
| 1967 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | English | 45 |
| 1968 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | Literature | 43 |
| 1969 | Brumer, Nicholas | Melbourne Grammar School | Melbourne | Psychology | 43 |
| 1970 | Brumley, Kyle | Emmanuel College Warrnambool | Warrnambool | Further Mathematics | 42 |
| 1971 | Brumley, Lauren | Toorak College | Mount Eliza | Visual Communication Design | 50 |