| 1822 | Briggs, Wade | Sandringham College | Sandringham | Theatre Studies | 42 |
| 1823 | Brighthope, Daniel | Brighton Grammar School | Brighton | Geography | 43 |
| 1824 | Brimblecombe, Jenna | Warrnambool College | Warrnambool | Biology | 44 |
| 1825 | Brinkley, Nicholas | Melbourne High School | South Yarra | Biology | 47 |
| 1826 | Brinkman, Simon | St Leonards College | Brighton East | Further Mathematics | 41 |
| 1827 | Brisbane, Timothy | Mentone Grammar School | Mentone | Specialist Mathematics | 43 |
| 1828 | Brisbane, Timothy | Mentone Grammar School | Mentone | Chemistry | 42 |
| 1829 | Brisbane, Timothy | Mentone Grammar School | Mentone | Physics | 42 |
| 1830 | Brislane, Elisa | Clonard College | Herne Hill | Psychology | 41 |
| 1831 | Bristow, Kate | Wantirna College | Wantirna | Legal Studies | 40 |
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| 1832 | Britee, Shaunna | Catholic Ladies College | Eltham | Business Administration (VCE VET) | 40 |
| 1833 | Britt, Carly | Catholic Regional College Drysdale | Drysdale | Legal Studies | 40 |
| 1834 | Britt, Carmel | Girton Grammar School | Bendigo | Further Mathematics | 40 |
| 1835 | Brittain, Kevin | St Josephs College Geelong | Newtown | Health and Human Development | 42 |
| 1836 | Britten, Cal | Mount Beauty Secondary College | Mount Beauty | Physical Education | 43 |
| 1837 | Britto, Jillian | MacRobertson Girls High School | Melbourne | Accounting | 41 |
| 1838 | Britto, Joanne | MacRobertson Girls High School | Melbourne | Literature | 47 |
| 1839 | Brkic, Carlia | Clonard College | Herne Hill | Further Mathematics | 42 |
| 1840 | Broadbent, Elizabeth | Ballarat Clarendon College | Ballarat | Legal Studies | 44 |
| 1841 | Broadstock, Daniel | Plenty Valley Christian College | Doreen | English | 47 |
| 1842 | Broadstock, Daniel | Centre for Adult Education | Melbourne | Drama | 42 |
| 1843 | Broadstock, Daniel | Plenty Valley Christian College | Doreen | History: Revolutions | 41 |
| 1844 | Brock, Adam | St Francis Xavier College | Beaconsfield | Multimedia (VCE VET) | 40 |
| 1845 | Brock, Carla | Grovedale College | Grovedale | Food and Technology | 42 |
| 1846 | Brock, Cassandra | Eltham High School | Eltham | Studio Arts | 43 |
| 1847 | Brockwell, Amie | Tintern Girls Grammar School | Ringwood East | Geography | 44 |
| 1848 | Broderick, Daniel | St Josephs College Geelong | Newtown | Food and Technology | 46 |
| 1849 | Broderick, Daniel | St Josephs College Geelong | Newtown | Further Mathematics | 42 |
| 1850 | Brodie, Frederick | Melbourne High School | South Yarra | Biology | 47 |
| 1851 | Brodie, Frederick | Melbourne High School | South Yarra | Languages: Indonesian Second Language | 46 |
| 1852 | Brodie, Frederick | Melbourne High School | South Yarra | Chemistry | 43 |
| 1853 | Brodie, Frederick | Melbourne High School | South Yarra | English | 43 |
| 1854 | Brodie, Frederick | Melbourne High School | South Yarra | Mathematical Methods | 43 |
| 1855 | Brody, Rebecca | Methodist Ladies College | Kew | English | 44 |
| 1856 | Brody, Rebecca | Methodist Ladies College | Kew | Psychology | 44 |
| 1857 | Brody, Rebecca | Methodist Ladies College | Kew | Languages: French | 43 |
| 1858 | Brody, Rebecca | Methodist Ladies College | Kew | Literature | 41 |
| 1859 | Broeren, Lauren | St Pauls Anglican Grammar School | Warragul | Studio Arts | 44 |
| 1860 | Brokenshire, Laura | Thomas Carr College | Tarneit | Further Mathematics | 40 |
| 1861 | Bromberg, Benjamin | St Michaels Grammar School | St Kilda | History: Revolutions | 45 |
| 1862 | Bromberg, Benjamin | St Michaels Grammar School | St Kilda | Psychology | 41 |
| 1863 | Bromberg, Benjamin | St Michaels Grammar School | St Kilda | English | 40 |
| 1864 | Bromfield, Joanna | Bendigo Senior Secondary College | Bendigo | Mathematical Methods | 44 |
| 1865 | Bromfield, Joanna | Bendigo Senior Secondary College | Bendigo | Languages: German | 43 |
| 1866 | Bromley, Alanna | Rutherglen High School | Rutherglen | English | 42 |
| 1867 | Brooke, Hamish | Beaconhills College Pakenham | Pakenham | Art | 40 |
| 1868 | Brooker, Victor | Ballarat Clarendon College | Ballarat | Health and Human Development | 43 |
| 1869 | Brookes, Alexandra | Siena College | Camberwell | English | 43 |
| 1870 | Brookes, Carolyn | Canterbury Girls Secondary College | Canterbury | Further Mathematics | 48 |
| 1871 | Brooks, James | Whitefriars College | Donvale | English Language | 45 |