| 1893 | Brown, Sarah | Ballarat Clarendon College | Ballarat | Australian History | 41 |
| 1894 | Brown, Sarah | East Doncaster Secondary College | Doncaster East | Information Processing and Management | 40 |
| 1895 | Brown, Sigiriya | Methodist Ladies College | Kew | Visual Communication Design | 49 |
| 1896 | Brown, Sigiriya | Methodist Ladies College | Kew | Further Mathematics | 43 |
| 1897 | Brown, Sigiriya | Methodist Ladies College | Kew | English | 41 |
| 1898 | Brown, Sigiriya | Methodist Ladies College | Kew | Art | 40 |
| 1899 | Brown, Simon | Goulburn Valley Grammar School | Shepparton | Outdoor and Environmental Studies | 42 |
| 1900 | Brown, Siobhan | Strathcona Girls Grammar School | Canterbury | English | 42 |
| 1901 | Browne, Annabelle | Melbourne Girls Grammar | South Yarra | English | 44 |
| 1902 | Browne, Annabelle | Melbourne Girls Grammar | South Yarra | Physical Education | 42 |
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| 1903 | Browne, Emma | Eltham College of Education | Research | History: Revolutions | 46 |
| 1904 | Browne, Emma | Eltham College of Education | Research | Legal Studies | 43 |
| 1905 | Browne, Grace | Siena College | Camberwell | Design and Technology | 44 |
| 1906 | Browne, Kate | Brauer College | Warrnambool | Physical Education | 42 |
| 1907 | Browne, Laura | Eltham College of Education | Research | Legal Studies | 45 |
| 1908 | Browne, Laura | Eltham College of Education | Research | Psychology | 43 |
| 1909 | Browne, Nicholas | St Kevins College | Toorak | Design and Technology | 42 |
| 1910 | Browne, Richard | The Grange P-12 College | Hoppers Crossing | Food and Technology | 42 |
| 1911 | Browne, Thomas | Eltham College of Education | Research | Hospitality: Food and Beverages (VCE VET) | 47 |
| 1912 | Browne, Thomas | Eltham College of Education | Research | Psychology | 46 |
| 1913 | Brownhill, Elizabeth | Firbank Grammar School | Brighton | English | 43 |
| 1914 | Brownhill, Elizabeth | Firbank Grammar School | Brighton | Legal Studies | 41 |
| 1915 | Brownhill, Elizabeth | Firbank Grammar School | Brighton | Psychology | 41 |
| 1916 | Browning, Jarrod | Copperfield College | Delahey | Further Mathematics | 40 |
| 1917 | Brownlee, Steven | Wantirna College | Wantirna | Mathematical Methods | 43 |
| 1918 | Brownlee, Steven | Wantirna College | Wantirna | Physics | 43 |
| 1919 | Brownlee, Steven | Wantirna College | Wantirna | English | 41 |
| 1920 | Brownstein, James | Melbourne High School | South Yarra | Legal Studies | 50 |
| 1921 | Brownstein, James | Melbourne High School | South Yarra | English | 47 |
| 1922 | Brownstein, James | Melbourne High School | South Yarra | Accounting | 46 |
| 1923 | Brownstein, Rachael | The Geelong College | Newtown | Biology | 40 |
| 1924 | Brownstein, Thomas | Wangaratta High School | Wangaratta | Further Mathematics | 40 |
| 1925 | Brozgul, Berta | Victorian College of the Arts Secondary School | Southbank | Music Group Performance | 48 |
| 1926 | Brozgul, Misty | MacRobertson Girls High School | Melbourne | Legal Studies | 46 |
| 1927 | Brozgul, Misty | MacRobertson Girls High School | Melbourne | Psychology | 46 |
| 1928 | Bruce, Duncan | Marian College Ararat | Ararat | Theatre Studies | 42 |
| 1929 | Bruce, Jack | Mallacoota P-12 College | Mallacoota | Design and Technology | 41 |
| 1930 | Bruce, Jessica | Emmaus College | Vermont South | Design and Technology | 43 |
| 1931 | Bruce, Ross | Flinders Christian Community College Tyabb | Tyabb | Biology | 40 |
| 1932 | Bruch, Cortney | Mount Scopus Memorial College | Burwood | Further Mathematics | 41 |
| 1933 | Bruch, Cortney | Mount Scopus Memorial College | Burwood | Media | 41 |
| 1934 | Bruggemann, Jonathon | Ballarat Clarendon College | Ballarat | English Language | 44 |
| 1935 | Brumby, Philippa | Ballarat Clarendon College | Ballarat | Legal Studies | 43 |
| 1936 | Brumby-Rendell, Charley | The Hamilton and Alexandra College | Hamilton | Mathematical Methods | 45 |
| 1937 | Brumby-Rendell, Charley | The Hamilton and Alexandra College | Hamilton | Literature | 42 |
| 1938 | Brumby-Rendell, Charley | The Hamilton and Alexandra College | Hamilton | Chemistry | 41 |
| 1939 | Brumby-Rendell, Charley | The Hamilton and Alexandra College | Hamilton | English | 41 |
| 1940 | Brumley, Lauren | Toorak College | Mount Eliza | Psychology | 43 |
| 1941 | Brumley, Lisa | Canterbury Girls Secondary College | Canterbury | Further Mathematics | 50 |
| 1942 | Brumley, Lisa | Canterbury Girls Secondary College | Canterbury | Mathematical Methods | 49 |