| 1901 | De La Salle College Revesby Heights | Revesby Heights | Legal Studies | 3 |
| 1902 | De La Salle College Revesby Heights | Revesby Heights | Mathematics | 3 |
| 1903 | De La Salle College Revesby Heights | Revesby Heights | Mathematics Extension 1 | 2 |
| 1904 | De La Salle College Revesby Heights | Revesby Heights | Mathematics Extension 2 | 1 |
| 1905 | De La Salle College Revesby Heights | Revesby Heights | Modern History | 2 |
| 1906 | De La Salle College Revesby Heights | Revesby Heights | Personal Development, Health and Physical Education | 4 |
| 1907 | De La Salle College Revesby Heights | Revesby Heights | Physics | 3 |
| 1908 | De La Salle College Revesby Heights | Revesby Heights | Studies of Religion I | 6 |
| 1909 | De La Salle College Revesby Heights | Revesby Heights | Visual Arts | 4 |
| 1910 | Delany College | Granville | Arabic Continuers | 1 |
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| 1911 | Delany College | Granville | Business Studies | 1 |
| 1912 | Delany College | Granville | Spanish Continuers | 1 |
| 1913 | Delany College | Granville | Studies of Religion I | 1 |
| 1914 | Deniliquin High School | Deniliquin | Agriculture | 2 |
| 1915 | Deniliquin High School | Deniliquin | Biology | 4 |
| 1916 | Deniliquin High School | Deniliquin | Business Studies | 1 |
| 1917 | Deniliquin High School | Deniliquin | Chemistry | 1 |
| 1918 | Deniliquin High School | Deniliquin | Community and Family Studies | 2 |
| 1919 | Deniliquin High School | Deniliquin | English (Advanced) | 1 |
| 1920 | Deniliquin High School | Deniliquin | Information Processes and Technology | 2 |
| 1921 | Deniliquin High School | Deniliquin | Legal Studies | 1 |
| 1922 | Deniliquin High School | Deniliquin | Mathematics | 1 |
| 1923 | Deniliquin High School | Deniliquin | Music 1 | 2 |
| 1924 | Deniliquin High School | Deniliquin | Personal Development, Health and Physical Education | 2 |
| 1925 | Denison College of Secondary Education Bathurst | Bathurst | Ancient History | 2 |
| 1926 | Denison College of Secondary Education Bathurst | Bathurst | Biology | 1 |
| 1927 | Denison College of Secondary Education Bathurst | Bathurst | Chemistry | 1 |
| 1928 | Denison College of Secondary Education Bathurst | Bathurst | Community and Family Studies | 1 |
| 1929 | Denison College of Secondary Education Bathurst | Bathurst | Economics | 1 |
| 1930 | Denison College of Secondary Education Bathurst | Bathurst | English (Advanced) | 1 |
| 1931 | Denison College of Secondary Education Bathurst | Bathurst | English Extension 1 | 2 |
| 1932 | Denison College of Secondary Education Bathurst | Bathurst | English Extension 2 | 1 |
| 1933 | Denison College of Secondary Education Bathurst | Bathurst | General Mathematics | 1 |
| 1934 | Denison College of Secondary Education Bathurst | Bathurst | Industrial Technology | 1 |
| 1935 | Denison College of Secondary Education Bathurst | Bathurst | Mathematics | 1 |
| 1936 | Denison College of Secondary Education Bathurst | Bathurst | Music 1 | 2 |
| 1937 | Denison College of Secondary Education Bathurst | Bathurst | Physics | 2 |
| 1938 | Denison College of Secondary Education Bathurst | Bathurst | Senior Science | 1 |
| 1939 | Denison College of Secondary Education Kelso | Kelso | English (Advanced) | 1 |
| 1940 | Denison College of Secondary Education Kelso | Kelso | English Extension 1 | 1 |
| 1941 | Denison College of Secondary Education Kelso | Kelso | English Extension 2 | 1 |
| 1942 | Denison College of Secondary Education Kelso | Kelso | History Extension | 1 |
| 1943 | Denison College of Secondary Education Kelso | Kelso | Industrial Technology | 2 |
| 1944 | Denison College of Secondary Education Kelso | Kelso | Mathematics Extension 1 | 1 |
| 1945 | Denison College of Secondary Education Kelso | Kelso | Modern History | 1 |
| 1946 | Domremy College | Five Dock | Ancient History | 3 |
| 1947 | Domremy College | Five Dock | Biology | 3 |
| 1948 | Domremy College | Five Dock | Economics | 1 |
| 1949 | Domremy College | Five Dock | English (Advanced) | 3 |
| 1950 | Domremy College | Five Dock | Food Technology | 2 |