| 1 | Abbotsleigh | Wahroonga | Latin Extension | Shen, Abby Yee |
| 2 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Bency, Carol |
| 3 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Chiu, Royce Lun Wai |
| 4 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Chung, Sally |
| 5 | Baulkham Hills High School | Baulkham Hills | Latin Extension | De Silva, Thanushka Shehani |
| 6 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Kennedy, Tom Joonas |
| 7 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Leung, Jovi |
| 8 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Li, Yuqing |
| 9 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Son, Jin Ju |
| 10 | Baulkham Hills High School | Baulkham Hills | Latin Extension | Stojnic, Petra |
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| 11 | Cranbrook School | Bellevue Hill | Latin Extension | North, Jack |
| 12 | Cranbrook School | Bellevue Hill | Latin Extension | Rastogi, Taje |
| 13 | Cranbrook School | Bellevue Hill | Latin Extension | Tasker, Tobias |
| 14 | Cranbrook School | Bellevue Hill | Latin Extension | Walker, James |
| 15 | Cranbrook School | Bellevue Hill | Latin Extension | Wardman, Hunter |
| 16 | North Sydney Boys High School | Crows Nest | Latin Extension | Feng, Edward |
| 17 | North Sydney Boys High School | Crows Nest | Latin Extension | John, Tanish |
| 18 | North Sydney Boys High School | Crows Nest | Latin Extension | Xue, Tim Jay |
| 19 | North Sydney Boys High School | Crows Nest | Latin Extension | Zeng, Chris Hao |
| 20 | North Sydney Boys High School | Crows Nest | Latin Extension | Zhang, Tong Xin |
| 21 | North Sydney Boys High School | Crows Nest | Latin Extension | Zou, Kevin Tinwing |
| 22 | North Sydney Girls High School | Crows Nest | Latin Extension | Clark-Lewis, Yvonne |
| 23 | North Sydney Girls High School | Crows Nest | Latin Extension | Stephenson, Edwina |
| 24 | North Sydney Girls High School | Crows Nest | Latin Extension | Yang, May May |
| 25 | North Sydney Girls High School | Crows Nest | Latin Extension | Zhu, Xinyi |
| 26 | Pymble Ladies College | Pymble | Latin Extension | Hou, Christy |
| 27 | Pymble Ladies College | Pymble | Latin Extension | Larkin, Hebe |
| 28 | Queenwood School for Girls | Mosman | Latin Extension | Li, Vanessa Sihui |
| 29 | SHORE Sydney Church of England Grammar School | North Sydney | Latin Extension | Ma, Anthony Bruce |
| 30 | SHORE Sydney Church of England Grammar School | North Sydney | Latin Extension | Muir, Lachlan William |
| 31 | SHORE Sydney Church of England Grammar School | North Sydney | Latin Extension | Wang, Chuyi |
| 32 | St George Girls High School | Kogarah | Latin Extension | Chan, Hillary Yvonne |
| 33 | St George Girls High School | Kogarah | Latin Extension | He, Louisa Wen Jing |
| 34 | St George Girls High School | Kogarah | Latin Extension | Thich, Yvonne |
| 35 | St Ignatius College | Lane Cove | Latin Extension | Gray, Jesse |
| 36 | St Ignatius College | Lane Cove | Latin Extension | Rickard, Xavier |
| 37 | St Ignatius College | Lane Cove | Latin Extension | Short, Benjamin |
| 38 | St Josephs College Hunters Hill | Hunters Hill | Latin Extension | McGregor, Thomas |
| 39 | Sydney Boys High School | Moore Park | Latin Extension | Balasooriya, Sanishka Randesh |
| 40 | Sydney Boys High School | Moore Park | Latin Extension | He, Anthony |
| 41 | Sydney Boys High School | Moore Park | Latin Extension | Yi, Roy Joon Yup |
| 42 | Sydney Girls High School | Surry Hills | Latin Extension | Chan, Glenda |
| 43 | Sydney Girls High School | Surry Hills | Latin Extension | Dervenis, Dimitra |
| 44 | Sydney Girls High School | Surry Hills | Latin Extension | McHugh, Max Lucy |
| 45 | Sydney Girls High School | Surry Hills | Latin Extension | Zou, Joanne |
| 46 | Sydney Grammar School | Darlinghurst | Latin Extension | Aggarwal, Ashwin |
| 47 | Sydney Grammar School | Darlinghurst | Latin Extension | Anura, Aravindh Hamsathvan |
| 48 | Sydney Grammar School | Darlinghurst | Latin Extension | Batt, Wyatt |
| 49 | Sydney Grammar School | Darlinghurst | Latin Extension | Esteban, Andrew |
| 50 | Sydney Grammar School | Darlinghurst | Latin Extension | Huynh, Jason |