This report shows the total number of VCE High Achiever awards won by students in each subject at each school in 2013.
| 1 | St Catherines School | Toorak | English | 38 |
| 2 | St Catherines School | Toorak | Business Management | 13 |
| 3 | St Catherines School | Toorak | Psychology | 10 |
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| 4 | St Catherines School | Toorak | Mathematical Methods | 8 |
| 5 | St Catherines School | Toorak | History: Revolutions | 7 |
| 6 | St Catherines School | Toorak | Art | 5 |
| 7 | St Catherines School | Toorak | Further Mathematics | 5 |
| 8 | St Catherines School | Toorak | Literature | 5 |
| 9 | St Catherines School | Toorak | Visual Communication Design | 5 |
| 10 | St Catherines School | Toorak | Biology | 4 |
| 11 | St Catherines School | Toorak | Economics | 4 |
| 12 | St Catherines School | Toorak | Health and Human Development | 4 |
| 13 | St Catherines School | Toorak | Studio Arts | 4 |
| 14 | St Catherines School | Toorak | Global Politics | 3 |
| 15 | St Catherines School | Toorak | Accounting | 2 |
| 16 | St Catherines School | Toorak | Languages: French | 2 |
| 17 | St Catherines School | Toorak | Chemistry | 1 |
| 18 | St Catherines School | Toorak | Physics | 1 |