This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2020.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Cammeraygal High School | Crows Nest | Polish Continuers | Kazmierski, Veronika |
| 2 | Canterbury Girls High School | Canterbury | Polish Continuers | Haloszka, Amber |
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| 3 | Clancy Catholic College | West Hoxton | Polish Continuers | Kopaczynski, Mateusz |
| 4 | Hunters Hill High School | Hunters Hill | Polish Continuers | Urbanczyk, Ivo |
| 5 | Magdalene Catholic College | Narellan | Polish Continuers | Serafin, Veronica |
| 6 | Mary MacKillop College | Wakeley | Polish Continuers | Pabijan, Belinda |
| 7 | Mount Carmel Catholic College | Varroville | Polish Continuers | Kawa, Tomasz |
| 8 | Newington College | Stanmore | Polish Continuers | Ciesielski, Lucas Adam |
| 9 | Penrith High School | Penrith | Polish Continuers | Zylka, Michael |
| 10 | Rose Bay Secondary College | Dover Heights | Polish Continuers | Friedrich, Veronica |
| 11 | St Marys Cathedral College | Sydney | Polish Continuers | Snoch, Gabriel |
| 12 | Winmalee High School | Winmalee | Polish Continuers | Baran, Adrianna |