This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2020.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Continuers | Grouva, Eleni |
| 2 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Continuers | Kyriakides, Victoria |
| 3 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Continuers | Saroukos, Chrysovalantou |
| 4 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Continuers | Stathakopoulou, Stamatia |
| 5 | Blakehurst High School | Blakehurst | Modern Greek Continuers | Hatch, Eugenia |
| 6 | Blakehurst High School | Blakehurst | Modern Greek Continuers | Larissa, Erica |
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| 7 | Bossley Park High School | Bossley Park | Modern Greek Continuers | Reppas, Peter |
| 8 | Burwood Girls High School | Croydon | Modern Greek Continuers | Sempsis, Pinelopi |
| 9 | Canterbury Girls High School | Canterbury | Modern Greek Continuers | Zacharakis, Maria |
| 10 | Endeavour Sports High School | Caringbah | Modern Greek Continuers | Metirtikas, Daniella |
| 11 | Georges River College Oatley Senior Campus | Oatley | Modern Greek Continuers | Ekmekdjian, Christina |
| 12 | Holy Cross College | Ryde | Modern Greek Continuers | Giakoumakis, George |
| 13 | Hunters Hill High School | Hunters Hill | Modern Greek Continuers | Manolis, Aris |
| 14 | Kingsgrove North High School | Kingsgrove | Modern Greek Continuers | Tsatas, Georgios |
| 15 | Kogarah High School | Kogarah | Modern Greek Continuers | Kontou, Maria |
| 16 | Marrickville High School | Marrickville | Modern Greek Continuers | Syka, Dimitra |
| 17 | Moorefield Girls High School | Kogarah | Modern Greek Continuers | Gaitani, Paraskevi-Georgia |
| 18 | Mount St Joseph Milperra | Milperra | Modern Greek Continuers | Parisi, Dimitra |
| 19 | Parramatta Marist High School | Westmead | Modern Greek Continuers | Kretsavos, Nicholas |
| 20 | Randwick Girls High School | Randwick | Modern Greek Continuers | Kritikos, Eleni |
| 21 | Santa Sabina College | Strathfield | Modern Greek Continuers | Moulos, Antonia |
| 22 | St Euphemia College | Bankstown | Modern Greek Continuers | Alavanos, Michael |
| 23 | St Euphemia College | Bankstown | Modern Greek Continuers | Mavropoulos, Helena |
| 24 | St Euphemia College | Bankstown | Modern Greek Continuers | Vetsikas, Nicholas |
| 25 | St Euphemia College | Bankstown | Modern Greek Continuers | Vetsikas, Sophia |
| 26 | St George Girls High School | Kogarah | Modern Greek Continuers | Kalogerakis, Katerina |
| 27 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | Antonopoulos, Teoni |
| 28 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | Dovellos, Mihalis |
| 29 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | Keramitzis, Gianni-Aristotelis |
| 30 | St Ursulas College | Kingsgrove | Modern Greek Continuers | Tsardaka, Ioanna |
| 31 | Sydney Technical High School | Bexley | Modern Greek Continuers | Harilaou, Nestor |
| 32 | Sylvania High School | Sylvania | Modern Greek Continuers | Kapsabelis, Maria |