This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2016.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | All Saints Catholic Senior College | Casula | Polish Continuers | Zajaczkowski, Adrian |
| 2 | Australian Institute of Music Senior Secondary College | Surry Hills | Polish Continuers | Warhol-Bernard, Olivia Victoria |
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| 3 | Blue Mountains Grammar School | Wentworth Falls | Polish Continuers | Chabros, Julia |
| 4 | Cherrybrook Technology High School | Cherrybrook | Polish Continuers | Kucharzewski, Claudia Kristina |
| 5 | Christian Brothers High School Lewisham | Lewisham | Polish Continuers | Adams-Dzierzba, Dominic |
| 6 | Christian Brothers High School Lewisham | Lewisham | Polish Continuers | Zak, Maksymilian |
| 7 | Killarney Heights High School | Killarney Heights | Polish Continuers | Kalczynska, Karolina |
| 8 | Mary MacKillop College | Wakeley | Polish Continuers | Kruk, Angela |
| 9 | Oakhill College | Castle Hill | Polish Continuers | Zychowska, Gabriela Emilia |
| 10 | Our Lady of Mercy College Parramatta | Parramatta | Polish Continuers | Pazdzior, Paulina |
| 11 | Rose Bay Secondary College | Dover Heights | Polish Continuers | Janiga, Robert Igor |
| 12 | Rose Bay Secondary College | Dover Heights | Polish Continuers | Jurkowska, Paulina |
| 13 | St Marys Senior High School | St Marys | Polish Continuers | Zdrojkowska, Karolina Zuzanna |
| 14 | Thomas Reddall High School | Ambarvale | Polish Continuers | Leja, Maksym |