This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2014.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Pymble Ladies College | Pymble | Classical Greek Continuers | Lind, Phoebe |
| 2 | Pymble Ladies College | Pymble | Classical Greek Continuers | Smith, Gemma |
| 3 | Pymble Ladies College | Pymble | Classical Greek Continuers | Wijetilaka, Shani |
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| 4 | St Spyridon College Senior School | Maroubra | Classical Greek Continuers | Arvanitakis, Katerina Dion |
| 5 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Barlin, George |
| 6 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Clarke, William |
| 7 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Hatzis, Phillip |
| 8 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Howe, Richard |
| 9 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Kynaston, Grant |
| 10 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Mohr, Jack |
| 11 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Payne, Deion |
| 12 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Stratton, James |
| 13 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Tsakiris, Constandinos |
| 14 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | Wijetunga, Asanka |
| 15 | Trinity Grammar School | Summer Hill | Classical Greek Continuers | Lai, Richard Jun Wei |