This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2012.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Brigidine College St Ives | St Ives | Italian Extension | Kopp, Alexandra |
| 2 | Camden High School | Camden | Italian Extension | van Dantzig, Bridget Rose |
| 3 | Casimir Catholic College | Marrickville | Italian Extension | Pioli, Niccolo |
| 4 | Casimir Catholic College | Marrickville | Italian Extension | Pioli, Rebecca |
| 5 | Cerdon College | Merrylands | Italian Extension | Walker, Talia |
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| 6 | Domremy College | Five Dock | Italian Extension | Celani, Chiara |
| 7 | Dulwich High School of Visual Arts and Design | Dulwich Hill | Italian Extension | Caveagna, Kelly |
| 8 | Frensham School | Mittagong | Italian Extension | Andrews, Chloe |
| 9 | International Grammar School | Ultimo | Italian Extension | Kawano, Anzu |
| 10 | International Grammar School | Ultimo | Italian Extension | Muscatello, Isabel |
| 11 | Kincoppal Rose Bay School of the Sacred Heart | Vaucluse | Italian Extension | Mansueto, Tamara |
| 12 | Loreto Kirribilli | Kirribilli | Italian Extension | de Cure-Ryan, Celeste Monique |
| 13 | Loreto Kirribilli | Kirribilli | Italian Extension | Donnelly, Lucy Margaret |
| 14 | Loreto Kirribilli | Kirribilli | Italian Extension | Osborn, Katherine Charlotte |
| 15 | Monte Sant Angelo Mercy College | North Sydney | Italian Extension | Reid, Georgia |
| 16 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Italian Extension | Marchi, Jessica |
| 17 | Penrith High School | Penrith | Italian Extension | Suzuki, Maya Lucy Webster |
| 18 | Presbyterian Ladies College Sydney | Croydon | Italian Extension | Salanitro-Chafei, Emily |
| 19 | Presbyterian Ladies College Sydney | Croydon | Italian Extension | Specker, Philippa |
| 20 | Pymble Ladies College | Pymble | Italian Extension | Presutti, Emma |
| 21 | Santa Sabina College | Strathfield | Italian Extension | Capacchione, Giselle |
| 22 | St Patricks College Strathfield | Strathfield | Italian Extension | Dal Cin, Matthew Jake |
| 23 | Sydney Grammar School | Darlinghurst | Italian Extension | Corsaro, Alexander |
| 24 | Sydney Grammar School | Darlinghurst | Italian Extension | Davenport, Mischa |
| 25 | Sydney Grammar School | Darlinghurst | Italian Extension | Nicols, Thomas |
| 26 | Sydney Grammar School | Darlinghurst | Italian Extension | Stead, Anthony |
| 27 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Italian Extension | Webb, Fabian |
| 28 | Trinity Catholic College Lismore | East Lismore | Italian Extension | Gardner-Marlin, Josephine |
| 29 | Trinity Catholic College Lismore | East Lismore | Italian Extension | Lennon, Tamara |