This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2008.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Pymble Ladies College | Pymble | Classical Greek Extension | So, Bonnie |
| 2 | Pymble Ladies College | Pymble | Classical Greek Extension | White, Rachel Lon Shuane |
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| 3 | SHORE Sydney Church of England Grammar School | North Sydney | Classical Greek Extension | Thompson, Alexander William |
| 4 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Gardiner, Sean |
| 5 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Jones, Harrison |
| 6 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Marinos, Emmanuel |
| 7 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Menzies, Matthew |
| 8 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Pope, Benjamin |
| 9 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Tan, Hanson |
| 10 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Vallance, Thomas |
| 11 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | Yedalian, Andrew |